Watch the Big Wing online guitar lesson by Jeff Scheetz from 50 Blues Rock Rhythms You MUST Know
One of Jimi's most notable "chordal picking" type songs would have to be "Little Wing". This riff will give you some of the techniques that make that song sound so sweet. There is also a move that you hear Jimi do many times, and that is the half step chromatic downward change. This is basically adding a passing chord in between two diatonic chords which gives you that trademark sound.